Activation of aqueous hydrogen peroxide for non-catalyzed dihydroperoxidation of ketones by azeotropic removal of water-Reference-Cited by-同舟云学术

Activation of aqueous hydrogen peroxide for non-catalyzed dihydroperoxidation of ketones by azeotropic removal of water

Published:2015 Issue:36 Volume:13 Page:9369-9372
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Starkl Renar K.¹²³⁴⁵,Pečar S.⁶⁷⁵,Iskra J.¹²³⁴⁵^ORCID

Affiliation:

1. Laboratory of Organic and Bioorganic Chemistry

2. Department of Physical and Organic Chemistry

3. Jožef Stefan Institute

4. Ljubljana

5. Slovenia

6. Faculty of Pharmacy

7. University of Ljubljana

Abstract

Cyclic and acyclic ketones were selectively converted to gem-dihydroperoxides in 72–99% yield with 30% aq. hydrogen peroxide by azeotropic distillation of water from the reaction mixture without any catalyst.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/OB/C5OB01503K

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