Palladium catalyzed chemo- and site-selective C–H acetoxylation and hydroxylation of oxobenzoxazine derivatives-Reference-Cited by-同舟云学术

Palladium catalyzed chemo- and site-selective C–H acetoxylation and hydroxylation of oxobenzoxazine derivatives

Published:2019 Issue:18 Volume:17 Page:4465-4469
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Bakthadoss Manickam¹²³⁴^ORCID,Vijay Kumar Polu¹²³⁴,Kumar Ravan¹²³⁴,Agarwal Vishal¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Pondicherry University

3. Pondicherry – 605 014

4. India

Abstract

A new protocol for the acetoxylation and hydroxylation of oxobenzoxazine derivatives via an ortho-C–H functionalization strategy using a palladium catalyst has been developed with chemo- and site-selectivity.

Funder

Science and Engineering Research Board

Council of Scientific and Industrial Research, India

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/OB/C9OB00642G

Reference67 articles.

1. Mechanochemical Synthesis of Substituted 4H-3,1-Benzoxazin-4-ones, 2-Aminobenzoxazin-4-ones, and 2-Amino-4H-3,1-benzothiazin-4-ones Mediated by 2,4,6-Trichloro-1,3,5-triazine and Triphenylphosphine

2. Copper-Catalyzed C–N Bond Formation/Rearrangement Sequence: Synthesis of 4H-3,1-Benzoxazin-4-ones

3. Palladium-Catalyzed Carbonylative Synthesis of Benzoxazinones from N-(o-Bromoaryl)amides Using Paraformaldehyde as the Carbonyl Source

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