Barluenga's reagent with HBF4as an efficient catalyst for alkyne-carbonyl metathesis of unactivated alkynes-Reference-Cited by-同舟云学术

Barluenga's reagent with HBF4as an efficient catalyst for alkyne-carbonyl metathesis of unactivated alkynes

Published:2016 Issue:44 Volume:14 Page:10352-10356
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Murai Kosuke¹²³⁴⁵,Tateishi Keiichiro¹²³⁴⁵,Saito Akio¹²³⁴⁵^ORCID

Affiliation:

1. Division of Applied Chemistry

2. Institute of Engineering

3. Tokyo University of Agriculture and Technology

4. Koganei

5. Japan

Abstract

Barluenga's reagent (IPy₂BF₄, Py = pyridine) treated with HBF₄efficiently catalyzes the inter- and intramolecular alkyne-carbonyl metathesis of unactivated alkynes. This work represents the first catalytic application of the Barluenga's reagent.

Funder

Japan Society for the Promotion of Science

Naito Foundation

Asahi Glass Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/OB/C6OB02090A

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