Unexpected formation of π-expanded isoquinoline from anthracene possessing four electron-donating groups via the Duff reaction-Reference-Cited by-同舟云学术

Unexpected formation of π-expanded isoquinoline from anthracene possessing four electron-donating groups via the Duff reaction

Published:2016 Issue:29 Volume:14 Page:7046-7052
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Węcławski Marek K.¹²³,Deperasińska Irena⁴⁵⁶³,Leniak Arkadiusz¹²³,Banasiewicz Marzena¹²³,Kozankiewicz Bolesław⁴⁵⁶³,Gryko Daniel T.¹²³

Affiliation:

1. Institute of Organic Chemistry Polish Academy of Sciences

2. Warsaw

3. Poland

4. Institute of Physics

5. Polish Academy of Sciences

6. 02-668 Warsaw

Abstract

An electron-rich derivative of anthracene reacts with hexamethylenetetramine under acidic conditions to give a rare heterocyclic scaffold possessing a pyridine moiety.

Funder

Narodowe Centrum Nauki

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/OB/C6OB00981F

Reference39 articles.

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2. 96. A new general method for the preparation of o-hydroxyaldehydes from phenols and hexamethylenetetramine

3. 282. Reactions between hexamethylenetetramine and phenolic compounds. Part II. Formation of phenolic aldehydes. Distinctive behaviour of p-nitrophenol

4. 71. A new method for the preparation of p-dialkylaminobenzaldehydes

5. Microwave-assisted synthesis, metallation, and duff formylation of porphyrins

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