Selective occupancy of methane by cage symmetry in TBAB ionic clathrate hydrate-Reference-Cited by-同舟云学术

Selective occupancy of methane by cage symmetry in TBAB ionic clathrate hydrate

Published:2016 Issue:32 Volume:52 Page:5621-5624
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Muromachi Sanehiro¹²³⁴,Udachin Konstantin A.⁵⁶⁷,Alavi Saman⁵⁶⁷,Ohmura Ryo⁸⁹¹⁰⁴,Ripmeester John A.⁵⁶⁷

Affiliation:

1. Research Institute of Energy Frontier

2. National Institute of Advanced Industrial Science and Technology (AIST)

3. Tsukuba

4. Japan

5. National Research Council of Canada

6. Ottawa

7. Canada

8. Department of Mechanical Engineering

9. Keio University

10. Yokohama 223-8522

Abstract

Methane trapped in the two distinct dodecahedral cages of the ionic clathrate hydrate of TBAB was studied by single crystal XRD and MD simulation.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C6CC00264A

Reference31 articles.

1. D. W. Davidson and J. A.Ripmeester, in Inclusion Compounds, ed. J. L. Atwood, J. E. D. Davies and D. D. MacNicol, Academic Press, London, 1984, ch. 3, vol. 3

2. The Diverse Nature of Dodecahedral Cages in Clathrate Hydrates As Revealed by 129Xe and 13C NMR Spectroscopy: CO2 as a Small-Cage Guest

3. A new clathrate hydrate structure

4. Molecular measurements of methane hydrate formation

5. Raman spectroscopic observations of methane-hydrate formation and hydrophobic hydration around methane molecules in solution

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