Adsorptive separation of cyclohexanol and cyclohexanone by nonporous adaptive crystals of RhombicArene

Author:

Zhao Yongye1,Xiao Hongyan1ORCID,Tung Chen-Ho1ORCID,Wu Li-Zhu1ORCID,Cong Huan1ORCID

Affiliation:

1. Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Key Laboratory of Bio-inspired Materials and Interfacial Science, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences & School of Future Technology, University of Chinese Academy of Sciences, Beijing, 100190, China

Abstract

The novel macrocycle RhombicArene features excellent capability for rapid, exclusive, and recyclable vapor adsorption of cyclohexanone in the presence of cyclohexanol, showing potential for energy-saving separation of these feedstock chemicals.

Funder

National Natural Science Foundation of China

Chinese Academy of Sciences

K. C. Wong Education Foundation

National Key Research and Development Program of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference53 articles.

1. W. B.Fisher and J. F.Van Peppen , in Kirk-Othmer Encyclopedia of Chemical Technology , John Wiley & Sons, Inc. , New York , 2000

2. M. T.Musser , in Ullmann's Encyclopedia of Industrial Chemistry , Wiley-VCH Verlag GmbH & Co. KGaA , 2000

3. Cyclohexane oxidation continues to be a challenge

4. Selective Phenol Hydrogenation to Cyclohexanone Over a Dual Supported Pd–Lewis Acid Catalyst

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