Rational design of flexible-linked 3D dimeric acceptors for stable organic solar cells demonstrating 19.2% efficiency

Author:

Zhang Zhe1,Yuan Shaohui2,Chen Tianqi2,Wang Jia2,Yi Yuan-Qiu-Qiang3,Zhao Bin4,Li Miaomiao4ORCID,Yao Zhaoyang1ORCID,Li Chenxi1,Wan Xiangjian1ORCID,Long Guankui2ORCID,Kan Bin2,Chen Yongsheng1ORCID

Affiliation:

1. State Key Laboratory and Institute of Elemento-Organic Chemistry, Frontiers Science Center for New Organic Matter, The Centre of Nanoscale Science and Technology and Key Laboratory of Functional Polymer Materials, Renewable Energy Conversion and Storage Center (RECAST), College of Chemistry, Nankai University, Tianjin 300071, China

2. School of Materials Science and Engineering, National Institute for Advanced Materials, Nankai University, Tianjin 300350, China

3. Division of Nano-Devices Research, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou 215123, China

4. School of Materials Science and Engineering, Tianjin Key Laboratory of Molecular Optoelectronic Science, Tianjin University, Tianjin 300072, China

Abstract

Efficient 3D dimeric acceptors linking two monomers with flexible alkyl linkers were developed. The resulting CH8-6-based OSCs achieved a high PCE of 19.2% and also exhibited excellent thermal stability and mechanical flexibility.

Funder

Ministry of Science and Technology of the People's Republic of China

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

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