The ON/OFF switching by metal ions of the “Sergeants and Soldiers” chiral amplification effect on helical poly(phenylacetylene)s
Author:
Affiliation:
1. Department of Organic Chemistry and Center for Research in Biological Chemistry and Molecular Materials (CIQUS)
2. University of Santiago de Compostela
3. E-15782 Santiago de Compostela, Spain
Abstract
Chiral amplification can be switched ON/OFF to both helical senses by the presence/absence of metal ions in copolymers of poly(phenylacetylene)s.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/SC/C3SC53330A
Reference38 articles.
1. Macromolecular stereochemistry: the out-of-proportion influence of optically active comonomers on the conformational characteristics of polyisocyanates. The sergeants and soldiers experiment
2. A Helical Polymer with a Cooperative Response to Chiral Information
3. The Macromolecular Route to Chiral Amplification
4. Photochemical Inversion of the Helical Twist Sense in Chiral Polyisocyanates
5. Synthesis and Conformational Study of Optically Active Poly(phenylacetylene) Derivatives Bearing a Bulky Substituent
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