Confinement of Fe–Al-PMOF catalytic sites favours the formation of pyrazoline from ethyl diazoacetate with an unusual sharp increase of selectivity upon recycling-Reference-Cited by-同舟云学术

Confinement of Fe–Al-PMOF catalytic sites favours the formation of pyrazoline from ethyl diazoacetate with an unusual sharp increase of selectivity upon recycling

Published:2018 Issue:73 Volume:54 Page:10308-10311
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Abeykoon Brian¹²³⁴⁵,Devic Thomas⁶⁷⁸⁹¹⁰,Grenèche Jean-Marc¹¹¹²¹³¹⁴¹⁵,Fateeva Alexandra¹²³⁴⁵^ORCID,Sorokin Alexander B.¹⁶¹⁷¹⁸¹⁹¹⁵^ORCID

Affiliation:

1. Univ. Lyon

2. Université Claude Bernard Lyon 1

3. Laboratoire des Multimatériaux et Interfaces (LMI)

4. UMR CNRS 5615

5. F-69622 Villeurbanne

6. Institut des Matériaux Jean Rouxel (IMN)

7. UMR 6502

8. Université de Nantes

9. CNRS

10. 44322 Nantes Cedex 3

11. Institut des Molécules et des Matériaux du Mans (IMMM)

12. UMR CNRS 6283

13. Le Mans Université

14. 72085 Le Mans Cedex

15. France

16. Institut de Recherches sur la Catalyse et l’Environnement de Lyon (IRCELYON)

17. UMR 5256

18. Université Claude Bernard Lyon 1 – CNRS

19. 69626 Villeurbanne

Abstract

Catalysis inside a porphyrinic MOF resulted in the formation of pyrazoline from ethyl diazoacetate which was not observed in the presence of a homogeneous iron porphyrin.

Funder

Centre National de la Recherche Scientifique

Université Claude Bernard Lyon 1

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC06082G

Reference27 articles.

1. Oxygen Activation and Radical Transformations in Heme Proteins and Metalloporphyrins

2. Metal–metalloporphyrin frameworks: a resurging class of functional materials

3. Metal–organic frameworks as solid catalysts for the synthesis of nitrogen-containing heterocycles

4. Metal organic frameworks as heterogeneous catalysts for the production of fine chemicals

5. Multifunctional metal–organic framework catalysts: synergistic catalysis and tandem reactions

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