Iodine-catalyzed aromatization of tetrahydrocarbazoles and its utility in the synthesis of glycozoline and murrayafoline A: a combined experimental and computational investigation-Reference-Cited by-同舟云学术

Iodine-catalyzed aromatization of tetrahydrocarbazoles and its utility in the synthesis of glycozoline and murrayafoline A: a combined experimental and computational investigation

Published:2014 Issue:27 Volume:12 Page:4832-4836
ISSN:1477-0520
Container-title:Org. Biomol. Chem.
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Humne Vivek¹²³⁴,Dangat Yuvraj⁵⁶⁴,Vanka Kumar⁵⁶⁴,Lokhande Pradeep¹²³⁴

Affiliation:

1. Center for Advance Studies

2. Department of Chemistry

3. University of Pune

4. Pune, India

5. Division of Physical Chemistry

6. CSIR-National Chemical Laboratory

Abstract

A new protocol for the aromatization of tetrahydrocarbazoles has been achieved using a catalytic amount of iodine. The role of iodine has been explained by DFT, and its scope is extended to the total synthesis of glycozoline and murrayafoline A.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/OB/C4OB00635F

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