Computational study on alkenyl/aryl C(sp2)–O homolytic cleavage of carboxylates and carbamates-Reference-Cited by-同舟云学术

Computational study on alkenyl/aryl C(sp2)–O homolytic cleavage of carboxylates and carbamates

Published:2016 Issue:32 Volume:6 Page:26514-26525
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Zheng Wenrui¹²³⁴,Ding Lanlan¹²³⁴,Wang Jiaoyang¹²³⁴,Wang Yingxing¹²³⁴

Affiliation:

1. College of Chemistry and Chemical Engineering

2. Shanghai University of Engineering Science

3. Shanghai 201620

4. China

Abstract

The alkenyl/aryl C(sp²)–O cleavage and the substituent effect in both carboxylates/carbamates and corresponding Ni complexes were investigated in detail by wB97 method.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C5RA27859G

Reference75 articles.

1. Exploration of New C−O Electrophiles in Cross-Coupling Reactions

2. Nickel-Catalyzed Cross-Couplings Involving Carbon−Oxygen Bonds

3. Combined Experimental and Theoretical Study on the Reductive Cleavage of Inert C–O Bonds with Silanes: Ruling out a Classical Ni(0)/Ni(II) Catalytic Couple and Evidence for Ni(I) Intermediates

4. Mechanisms and Origins of Switchable Chemoselectivity of Ni-Catalyzed C(aryl)–O and C(acyl)–O Activation of Aryl Esters with Phosphine Ligands

5. Directed ortho metalation. Tertiary amide and O-carbamate directors in synthetic strategies for polysubstituted aromatics

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