Modulating the ground state, stability and charge transport in OFETs of biradicaloid hexahydro-diindenopyrene derivatives and a proposed method to estimate the biradical character-Reference-Cited by-同舟云学术

Modulating the ground state, stability and charge transport in OFETs of biradicaloid hexahydro-diindenopyrene derivatives and a proposed method to estimate the biradical character

Published:2020 Issue:44 Volume:11 Page:12194-12205
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Jousselin-Oba Tanguy¹²³⁴⁵,Mamada Masashi⁶⁷⁸⁹¹⁰^ORCID,Okazawa Atsushi¹¹¹²¹³¹⁴¹⁵^ORCID,Marrot Jérome¹²³⁴⁵,Ishida Takayuki¹⁶¹⁷¹⁸¹⁵^ORCID,Adachi Chihaya⁶⁷⁸⁹¹⁰^ORCID,Yassar Abderrahim¹⁹²⁰²¹²²²³^ORCID,Frigoli Michel¹²³⁴⁵^ORCID

Affiliation:

1. UMR CNRS 8180

2. UVSQ

3. Institut Lavoisier de Versailles

4. Université Paris-Saclay

5. 78035 Versailles Cedex

6. Center for Organic Photonics and Electronics Research (OPERA)

7. JST ERATO Adachi Molecular Exciton Engineering Project

8. Academia-Industry Molecular Systems for Devices Research and Education Center

9. Kyushu University

10. Fukuoka

11. Division of Chemistry

12. Institute of Liberal Education

13. Nihon University School of Medicine

14. Tokyo 173-8610

15. Japan

16. Department of Engineering Science

17. The University of Electro-Communications

18. Tokyo 182-8585

19. Ecole Polytechnique

20. Institut Polytechnique de Paris

21. LPICM

22. CNRS

23. 91128 Palaiseau

Abstract

Biradicaloid HDIP derivatives show that the ΔE_S–T gap does not follow the reverse trend of the biradical character but depends more on the delocalization of the radical centres at the outer rings.

Funder

Japan Society for the Promotion of Science

Japan Science and Technology Agency

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC04583G

Reference62 articles.

1. Low band gap polycyclic hydrocarbons: from closed-shell near infrared dyes and semiconductors to open-shell radicals