Crown ether adducts of light alkali metal triphenylsilyls: synthesis, structure and hydrosilylation catalysis-Reference-Cited by-同舟云学术

Crown ether adducts of light alkali metal triphenylsilyls: synthesis, structure and hydrosilylation catalysis

Published:2014 Issue:38 Volume:43 Page:14315-14321
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Leich Valeri¹²³,Lamberts Kevin¹²³,Spaniol Thomas P.¹²³,Okuda Jun¹²³

Affiliation:

1. Institute of Inorganic Chemistry

2. RWTH Aachen University

3. D-52056 Aachen, Germany

Abstract

Alkali metal triphenylsilyls [Li(12-crown-4)SiPh₃]·(thf)_0.5, [Na(15-crown-5)SiPh₃]·(thf)_0.5 and [K(18-crown-6)SiPh₃(thf)] were synthesized using 1,1,1-trimethyl-2,2,2-triphenyldisilane and shown to catalyze the regioselective hydrosilylation of 1,1-diphenylethene.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT00916A

Reference60 articles.

1. Z. Rappoport and Y.Apeloig , The Chemistry of Organic Silicon Compounds , Wiley & Sons , New York , 2000

2. Silicon derivatives of the metals of groups 1 and 2

3. Lithiosilanes and their application to the synthesis of polysilane dendrimers

4. Silyl Anions

5. Syntheses of γ,δ-unsaturated alcohols from allylsilanes and carbonyl compounds in the presence of titanium tetrachloride

Cited by 28 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Nascent developments in main group element-catalyzed hydrosilylation and dehydrogenative silylation of alkenes and alkynes;Organic Chemistry Frontiers;2024

2. Trends in the Electronic Structure and Chemical Bonding of a Series of Porphyrinoid–Uranyl Complexes;Inorganic Chemistry;2023-03-29

3. Formal Hydrotrimethylsilylation of Styrenes with Anti-Markovnikov Selectivity Using Hexamethyldisilane;Organic Letters;2022-11-24

4. Hydrofunctionalization ofCarbon–CarbonDouble Bonds;Addition Reactions with Unsaturated Hydrocarbons;2022-03-04

5. Molecular Main Group Metal Hydrides;Chemical Reviews;2021-08-27