Phosphorus–nitrogen compounds. Part 54. syntheses of chiral amino-4-fluorobenzyl-spiro(N/O)cyclotriphosphazenes: structural and stereogenic properties

Author:

Mutlu Ömer Faruk123,Binici Arzu453,Okumuş Aytuğ6753ORCID,Elmas Gamze6753ORCID,Çoşut Bünyemin6893,Kılıç Zeynel6753ORCID,Hökelek Tuncer1011123

Affiliation:

1. Turkish Medicines and Medical Devices Agency

2. 06520 Ankara

3. Turkey

4. Republic of Turkey Ministry of Health

5. 06100 Ankara

6. Department of Chemistry

7. Ankara University

8. Gebze Technical University

9. 41400 Gebze-Kocaeli

10. Department of Physics

11. Hacettepe University

12. 06800 Ankara

Abstract

Syntheses, spectral and crystallographic characterizations and stereogenic properties by 31P NMR spectra recorded with the addition of CSA, CD spectra and chiral HPLC of amino-4-fluorobenzylspiro(N/O)cyclotriphosphazenes were examined.

Funder

Türkiye Bilimler Akademisi

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference49 articles.

1. V. Chandrasekhar and A.Chakraborty , Organophosphorus Chemistry , Royal Society of Chemistry (RSC Publishing) , 2019 , vol. 48, pp. 400–423

2. V. Chandrasekhar and A.Chakraborty , Organophosphorus Chemistry , Royal Society of Chemistry (RSC Publishing) , 2020 , vol. 49, pp. 349–376

3. Recent advances in the supramolecular assembly of cyclophosphazene derivatives

4. The reactivity of the cyclic systems (NPCl2)3−n(NSOX)n (n = 0,1; X = Cl, Ph) towards aziridine

5. Aziridinolysis patterns of (NPCl2)3 and (NPCl2)4; crystal structures of trans-N3P3(NC2H4)2Cl4 and 2,trans-4-N4P4(NC2H4)2Cl6

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