Stabilization of pentazolate anions in the high-pressure compounds Na2N5 and NaN5 and in the sodium pentazolate framework NaN5·N2

Author:

Bykov Maxim12345ORCID,Bykova Elena5634ORCID,Chariton Stella7894ORCID,Prakapenka Vitali B.7894ORCID,Batyrev Iskander G.10114,Mahmood Mohammad F.1234,Goncharov Alexander F.5634ORCID

Affiliation:

1. Department of Mathematics

2. Howard University

3. Washington

4. USA

5. The Earth and Planets Laboratory

6. Carnegie Institution for Science

7. Center for Advanced Radiation Sources

8. University of Chicago

9. Lemont

10. U.S. Army Research Laboratory

11. Aberdeen Proving Ground

Abstract

Three oxygen-free pentazolate salts Na2N5, NaN5 and NaN5·N2 were synthesized from sodium azide NaN3 and molecular nitrogen N2 at 50 GPa.

Funder

National Science Foundation

Argonne National Laboratory

Army Research Laboratory

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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