Response of a Zn(ii)-based metal–organic coordination polymer towards trivalent metal ions (Al3+, Fe3+ and Cr3+) probed by spectroscopic methods-Reference-Cited by-同舟云学术

Response of a Zn(ii)-based metal–organic coordination polymer towards trivalent metal ions (Al3+, Fe3+ and Cr3+) probed by spectroscopic methods

Published:2021 Issue:21 Volume:50 Page:7388-7399
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Daga Pooja¹²³⁴⁵^ORCID,Manna Priyanka¹⁶⁷⁵,Majee Prakash¹²³⁴⁵^ORCID,Singha Debal Kanti¹²³⁴⁵^ORCID,Hui Sayani¹⁶⁷⁵^ORCID,Ghosh Ananta Kumar¹⁸⁹⁵,Mahata Partha¹⁶⁷⁵^ORCID,Mondal Sudip Kumar¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Siksha-Bhavana

3. Visva-Bharati University

4. Santiniketan-731235

5. India

6. Jadavpur University

7. Kolkata-700 032

8. Burdwan Raj College

9. Burdwan-713104

Abstract

A Zn-based MOCP showed non-monotonous luminescence responses towards Al³⁺, Cr³⁺ and Fe³⁺ due to complexation based on hard–hard acid–base interactions that resulted in increased rigidity for Al³⁺ and LMCT using vacant d-orbitals of Cr³⁺ and Fe³⁺.

Funder

Department of Science and Technology, Ministry of Science and Technology, India

Jadavpur University

University Grants Commission

Council of Scientific and Industrial Research, India

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT00729G

Reference71 articles.