Homogeneous vs. heterogeneous: mechanistic insights into iron group metal-catalyzed reductions from poisoning experiments

Author:

Gärtner Dominik123,Sandl Sebastian4563ORCID,Jacobi von Wangelin Axel4563ORCID

Affiliation:

1. Merck Healthcare KGaA

2. 64293 Darmstadt

3. Germany

4. Dept. of Chemistry

5. University of Hamburg

6. 20146 Hamburg

Abstract

Iron group catalysts constitute a promising alternative to well-established noble metal catalysts in reduction reactions. This review advocates the use of kinetic poisoning experiments to distinguish between homotopic and heterotopic mechanisms.

Funder

H2020 European Research Council

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Reference114 articles.

1. The Handbook of Homogeneous Hydrogenation , ed. J. G. de Vries and C. J. Elsevier , Wiley , Weinheim , 2007

2. Metal-Catalyzed Cross-Coupling Reactions and More , ed. A. de Meijere , S. Bräse and M. Oestreich , Wiley , Weinheim , 2014

3. Catalysis Without Non-Precious Metals , ed. R. M. Bullock , Wiley , Weinheim , 2010 ;

4. Non-Noble Metal Catalysis , ed. R. J. M. Klein Gebbink and M.-E. Moret , Wiley , Weinheim , 2018

5. Homogeneous Hydrogenation with Non-Precious Catalysts , ed. J. F. Teichert , Wiley , Weinheim , 2019

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