InI<sub>3</sub>-catalyzed polyene cyclization of allenes and its application in the total synthesis of seven abietane-type diterpenoids-Reference-Cited by-同舟云学术

InI₃-catalyzed polyene cyclization of allenes and its application in the total synthesis of seven abietane-type diterpenoids

Published:2022 Issue:46 Volume:13 Page:13893-13897
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Huo Chen-Yu¹,Zheng Tian-Lu¹,Dai Wei-Hao¹,Zhang Zi-Hao¹,Wang Jin-Da¹,Zhu Dao-Yong¹²,Wang Shao-Hua¹^ORCID,Zhang Xiao-Ming¹^ORCID,Xu Xue-Tao³^ORCID

Affiliation:

1. School of Pharmacy & State Key Laboratory of Applied Organic Chemistry, Lanzhou University, 730000, P. R. China

2. Key Laboratory of Drug-Targeting of Education Ministry and Department of Medicinal Chemistry, West China School of Pharmacy, Sichuan University, Chengdu, 610041, P. R. China

3. School of Biotechnology and Health Science, Wuyi University, Jiangmen 529020, P. R. China

Abstract

A polyene cyclization mode using the allene group as the initiator has been successfully developed, and its potential utility has been well demonstrated by the collective synthesis of seven abietane-type diterpenoids.

Funder

National Natural Science Foundation of China

Science and Technology Program of Gansu Province

Department of Education of Guangdong Province

Fundamental Research Funds for the Central Universities

Lanzhou University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC04229K