Electrochemical radical reactions of alkyl iodides: a highly efficient, clean, green alternative to tin reagents
Author:
Affiliation:
1. Department of Chemistry
2. University College London
3. London WC1H 0AJ
4. UK
Abstract
A ‘green’ and high-yielding electrochemical method for performing tin-free, intermolecular radical reactions (the Giese reaction) has been developed.
Funder
Leverhulme Trust
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC01694B
Reference32 articles.
1. Synthetic methods. Part (i): Free-radical reactions
2. P. Renaud and M. P.Sibi , Radicals in Organic Synthesis , Wiley-VCH , Weinheim, Germany , 2001 , vol. 1 and 2
3. Flight from the Tyranny of Tin: The Quest for Practical Radical Sources Free from Metal Encumbrances
4. Engaging unactivated alkyl, alkenyl and aryl iodides in visible-light-mediated free radical reactions
5. Photochemical generation of radicals from alkyl electrophiles using a nucleophilic organic catalyst
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