Highly oxidized U(<scp>vi</scp>) within the smallest fullerene: gas-phase synthesis and computational study of boron-doped U@C<sub>27</sub>B-Reference-Cited by-同舟云学术

Highly oxidized U(vi) within the smallest fullerene: gas-phase synthesis and computational study of boron-doped U@C₂₇B

Published:2023 Issue:3 Volume:10 Page:908-914
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Moreno-Vicente Antonio¹,Alías-Rodríguez Marc¹²,Dunk Paul W.³,de Graaf Coen¹⁴^ORCID,Poblet Josep M.¹^ORCID,Rodríguez-Fortea Antonio¹^ORCID

Affiliation:

1. Departament Química Física i Inorgànica, Universitat Rovira i Virgili, C/Marcel·lí Domingo 1, 43007, Tarragona, Spain

2. Aix-Marseille Univ, CNRS, ICR, Marseille, France

3. National High Magnetic Field Laboratory, Florida State University, 1800 East Paul Dirac Drive, Tallahassee, FL 32310, USA

4. ICREA, Pg Lluis Companys 23, 08010, Barcelona, Spain

Abstract

The smallest borafullerene U@C27B has been synthesized using a laser vaporization cluster source. The U atom, placed in the middle of the cage and interacting with all the 28 atoms, is formally described as highly oxidized U(vi).

Funder

Ministerio de Ciencia e Innovación

Agència de Gestió d’Ajuts Universitaris i de Recerca

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QI/D2QI02160A

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