Dialing in single-site reactivity of a supported calixarene-protected tetrairidium cluster catalyst-Reference-Cited by-同舟云学术

Dialing in single-site reactivity of a supported calixarene-protected tetrairidium cluster catalyst

Published:2017 Issue:7 Volume:8 Page:4951-4960
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Palermo Andrew¹²³⁴,Solovyov Andrew⁵⁶⁷⁴,Ertler Daniel⁵⁶⁷⁴,Okrut Alexander⁵⁶⁷⁴,Gates Bruce C.¹²³⁴,Katz Alexander⁵⁶⁷⁴^ORCID

Affiliation:

1. Department of Chemical Engineering

2. University of California at Davis

3. Davis

4. USA

5. Department of Chemical and Biomolecular Engineering

6. University of California at Berkeley

7. Berkeley

Abstract

A closed Ir₄ carbonyl cluster, 1, comprising a tetrahedral metal frame and three tert-butyl-calix[4]arene(OPr)₃(OCH₂PPh₂) (Ph = phenyl; Pr = propyl) ligands at the basal plane, was silica supported and consists of “*” and “S” sites, which could be dialed in selectively for controlling ethylene hydrogenation catalysis.

Funder

Basic Energy Sciences

Chevron

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/SC/C7SC00686A

Reference73 articles.

1. Design of Heterogeneous Catalysts for Fuels and Chemicals Processing: An Overview

2. Discovery, Development, and Commercialization of Gold Catalysts for Acetylene Hydrochlorination