Ionic-liquid-assisted synthesis of the phosphorus interhalides [PBr4][IBr2] and [PBr4][I5Br7]-Reference-Cited by-同舟云学术

Ionic-liquid-assisted synthesis of the phosphorus interhalides [PBr4][IBr2] and [PBr4][I5Br7]

Published:2016 Issue:41 Volume:45 Page:16526-16532
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Hausmann David¹²³⁴,Köppe Ralf¹²³⁴,Wolf Silke¹²³⁴,Roesky Peter W.¹²³⁴,Feldmann Claus¹²³⁴

Affiliation:

1. Institut für Anorganische Chemie

2. Karlsruhe Institute of Technology (KIT)

3. D-76131 Karlsruhe

4. Germany

Abstract

Ionic-liquid based synthesis results in the phosphorus interhalides [PBr₄][IBr₂] and [PBr₄]₂[I₅Br₇] whereof the latter shows thermal halogen release of 96.8 wt% (≤300 °C).

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT03303B

Reference47 articles.

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4. Structural Proof for the First Dianion of a Polychloride: Investigation of [Cl8]2−

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