Enantioselective difunctionalization of alkenes by a palladium-catalyzed Heck/borylation sequence-Reference-Cited by-同舟云学术

Enantioselective difunctionalization of alkenes by a palladium-catalyzed Heck/borylation sequence

Published:2022 Issue:7 Volume:13 Page:2021-2025
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Wu Yuanqi¹,Wu Lizuo¹,Zhang Zhan-Ming²,Xu Bing²,Liu Yu¹^ORCID,Zhang Junliang²

Affiliation:

1. Jilin Provincial Key Laboratory of Carbon Fiber Development and Application, College of Chemistry and Life Science, Advanced Institute of Materials Science, Changchun University of Technology, Changchun, 130012, P. R. China

2. Department of Chemistry, Fudan University, 2005 Songhu Road, Shanghai, 200438, P. R. China

Abstract

A palladium catalyzed enantioselective Heck/borylation reaction of alkene-tethered aryl iodides was realized, delivering a variety of 2,3-dihydrobenzofuranyl boronic esters in high yield with excellent enantioselectivity.

Funder

National Natural Science Foundation of China

E-Institutes of Shanghai Municipal Education Commission

Shanghai Municipal Education Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D1SC06229H

Reference62 articles.

1. Transition-metal-catalyzed Suzuki–Miyaura cross-coupling reactions: a remarkable advance from palladium to nickel catalysts