Iron(<scp>ii</scp>) spin crossover complexes of tetradentate Schiff-bases: tuning <i>T</i><sub>1/2</sub> by choice of formyl-heterocycle component-Reference-Cited by-同舟云学术

Iron(ii) spin crossover complexes of tetradentate Schiff-bases: tuning T_1/2 by choice of formyl-heterocycle component

Published:2024 Issue:26 Volume:53 Page:10974-10981
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Robb Matthew G.¹^ORCID,Chong Shen V.²^ORCID,Brooker Sally¹^ORCID

Affiliation:

1. Department of Chemistry and MacDiarmid Institute of Advanced Materials and Nanotechnology, University of Otago, P.O. Box 56, Dunedin 9054, New Zealand

2. Robinson Research Institute, School of Engineering, Victoria University of Wellington, PO Box 33436, Lower Hutt 5046, New Zealand

Abstract

Heterocycle choice in four structurally characterised solvent-free [FeII(Lheterocycle)(NCS)2] complexes of easily accessed Schiff base ligands strongly influences solid state spin crossover behaviour.

Funder

University of Otago

MacDiarmid Institute for Advanced Materials and Nanotechnology

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT00884G

Reference46 articles.

1. Complete solid state photoisomerization of bis(dipyrazolylstyrylpyridine)iron(ii) to change magnetic properties

2. Assessing the Impact of Electronic and Steric Tuning of the Ligand in the Spin State and Catalytic Oxidation Ability of the FeII(Pytacn) Family of Complexes

3. Steric and Electronic Control of the Spin State in Three-Fold Symmetric, Four-Coordinate Iron(II) Complexes

4. A Unified Treatment of the Relationship Between Ligand Substituents and Spin State in a Family of Iron(II) Complexes

5. Substituent effect of the coordinated pyridine in a series of pyrazolato bridged dinuclear diiron(ii) complexes on the spin-crossover behavior