Gas phase 1H NMR studies and kinetic modeling of dihydrogen isotope equilibration catalyzed by Ru-nanoparticles under normal conditions: dissociative vs. associative exchange-Reference-Cited by-同舟云学术

Gas phase 1H NMR studies and kinetic modeling of dihydrogen isotope equilibration catalyzed by Ru-nanoparticles under normal conditions: dissociative vs. associative exchange

Published:2018 Issue:16 Volume:20 Page:10697-10712
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Limbach Hans-Heinrich¹²³⁴^ORCID,Pery Tal¹²³⁴,Rothermel Niels⁵⁶⁷⁴,Chaudret Bruno⁸⁹¹⁰¹¹¹²^ORCID,Gutmann Torsten⁵⁶⁷⁴^ORCID,Buntkowsky Gerd⁵⁶⁷⁴^ORCID

Affiliation:

1. Institut für Chemie und Biochemie

2. Freie Universität Berlin

3. D-14195 Berlin

4. Germany

5. Eduard-Zintl-Institut für Anorganische und Physikalische Chemie

6. Technische Universität Darmstadt

7. D-64287 Darmstadt

8. Laboratoire de Physique et Chimie des Nano Objets

9. LPCNO

10. Institut National des Sciences Appliquées

11. Toulouse 31077

12. France

Abstract

Exposure of surface H-containing Ru-nanoparticles to D₂ gas produces HD via associative adsorption, surface H-transfer and associative desorption.

Funder

Deutsche Forschungsgemeinschaft

Centre National de la Recherche Scientifique

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CP/C7CP07770J

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4. The adsorption of hydrogen on ruthenium (001): Adsorption states, dipole moments and kinetics of adsorption and desorption

5. First-principles study of hydrogen adsorption on Ru(0001): Possible occupation of subsurface sites

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