Optimised synthesis of monoanionic bis(NHC)-pincer ligand precursors and their Li-complexes-Reference-Cited by-同舟云学术

Optimised synthesis of monoanionic bis(NHC)-pincer ligand precursors and their Li-complexes

Published:2016 Issue:11 Volume:40 Page:9160-9169
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Jürgens Eva¹²³⁴,Buys Kai N.⁵⁶⁷⁸,Schmidt Anna-Theresa¹²³⁴,Furfari Samantha K.⁵⁶⁷⁸^ORCID,Cole Marcus L.⁵⁶⁷⁸,Moser Michael⁹¹⁰¹¹⁴,Rominger Frank⁹¹⁰¹¹⁴,Kunz Doris¹²³⁴⁹^ORCID

Affiliation:

1. Institut für Anorganische Chemie

2. Eberhard Karls Universität Tübingen

3. D-72076 Tübingen

4. Germany

5. School of Chemistry

6. University of New South Wales

7. Sydney

8. Australia

9. Organisch-Chemisches Institut

10. Ruprecht-Karls Universität Heidelberg

11. D-69120 Heidelberg

Abstract

A straightforward preparation of bis(imidazol)carbazole 4 from carbazole, its transformation to various bis(imidazolium) salts and their deprotonation to Li carbene complexes is presented.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/NJ/C6NJ01941B

Reference44 articles.

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2. Pincer Complexes of Lithium, Sodium, Magnesium and Related Metals: A Discussion of Solution and Solid-State Aggregated Structure and Reactivity

3. A Pd complex of a tridentate pincer CNC bis-carbene ligand as a robust homogenous Heck catalyst

4. The synthesis of a di-N-heterocyclic carbene-amido complex of palladium(ii)

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