Synthesis of a highly reactive form of WO2Cl2, its conversion into nanocrystalline mono-hydrated WO3 and coordination compounds with tetramethylurea-Reference-Cited by-同舟云学术

Synthesis of a highly reactive form of WO2Cl2, its conversion into nanocrystalline mono-hydrated WO3 and coordination compounds with tetramethylurea

Published:2016 Issue:39 Volume:45 Page:15342-15349
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Bortoluzzi Marco¹²³⁴,Evangelisti Claudio⁵⁶⁴,Marchetti Fabio⁷⁸⁹⁴,Pampaloni Guido⁷⁸⁹⁴,Piccinelli Fabio¹⁰¹¹¹²¹³⁴,Zacchini Stefano¹⁴¹⁵¹⁶⁴

Affiliation:

1. Università di Venezia Ca’ Foscari

2. Dipartimento di Scienze Molecolari e Nanosistemi

3. I-30170 Mestre

4. Italy

5. Istituto di Scienze e Tecnologie Molecolari (ISTM-CNR)

6. I-20138 Milano

7. Università di Pisa

8. Dipartimento di Chimica e Chimica Industriale

9. I-56124 Pisa

10. Università di Verona

11. Dipartimento di Biotecnologie

12. Laboratorio di Chimica dello Stato Solido

13. I-37134 Verona

14. Università di Bologna

15. Dipartimento di Chimica Industriale “Toso Montanari”

16. I-40136 Bologna

Abstract

A new form of WO₂Cl₂ was prepared from WCl₆. Conversion of WO₂Cl₂ into nanocrystalline WO₃·H₂O occurred upon air exposure at room temperature. The first coordination complexes of WO₂Cl₂ with an alkylurea are reported.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT02997C

Reference75 articles.

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5. Reduction of sulfoxides catalyzed by oxo-complexes

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