Molecular rotational conformation controls the rate of singlet fission and triplet decay in pentacene dimers-Reference-Cited by-同舟云学术

Molecular rotational conformation controls the rate of singlet fission and triplet decay in pentacene dimers

Published:2022 Issue:17 Volume:13 Page:4944-4954
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Ringström Rasmus¹^ORCID,Edhborg Fredrik¹,Schroeder Zachary W.²,Chen Lan²,Ferguson Michael J.²^ORCID,Tykwinski Rik R.²,Albinsson Bo¹^ORCID

Affiliation:

1. Department of Chemistry and Chemical Engineering, Chalmers University of Technology, Kemigården 4 SE-412 96, Göteborg, Sweden

2. Department of Chemistry, University of Alberta, Edmonton, Alberta T6G 2G2, Canada

Abstract

In this study we show that one molecule can have vastly different singlet fission and triplet recombination rates depending on its rotational freedom and the relative orientation of the pentacene moieties.

Funder

Vetenskapsrådet

Energimyndigheten

Natural Sciences and Engineering Research Council of Canada

Alberta Innovates

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D1SC06285A

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