Searching for novel reusable biomass-derived solvents: furfuryl alcohol/water azeotrope as a medium for waste-minimised copper-catalysed azide–alkyne cycloaddition

Author:

Rasina Dace12345,Lombi Aurora12345,Santoro Stefano12345,Ferlin Francesco12345,Vaccaro Luigi12345ORCID

Affiliation:

1. Laboratory of Green Synthetic Organic Chemistry

2. CEMIN – Dipartimento di Chimica

3. Biologia e Biotecnologie

4. Università di Perugia

5. 06123 Perugia

Abstract

Herein we report the first application of the furfuryl alcohol/water azeotrope as a sustainable and easily recoverable reaction medium for organic chemistry. As first applicantion we have defined a waste-oinimized protocol for click-chemistry synthesi of 1,2,3-triazoles.

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Reference102 articles.

1. J. Clarke and F.Deswarte, in Introduction to Chemicals from Biomass, ed. J. Clarke and F. Deswarte, John Wiley & Sons, Ltd, 2008, pp. 1–28

2. Star-Colibri, funded under the Seventh framework Programme of the European Union , Joint European Biorefinery Vision for 2030, 2011, http://www.star-colibri.eu/files/files/vision-web.pdf

3. U.S. Department of Energy , Biomass as Feedstock for a Bioenergy and Bioproducts Industry: The Technical Feasibility of a Billion-Ton Annual Supply, 2005, https://www1.eere.energy.gov/bioenergy/pdfs/final_billionton_vision_report2.pdf

4. Organisation for Economic Co-operation and Development , The Bioeconomy to 2030: Designing a Policy Agenda, 2009, http://www.oecd.org/futures/longtermtechnologicalsocietalchallenges/42837897.pdf

5. Catalytic conversion of biomass to biofuels

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