Synthetic feasibility of oxygen-driven photoisomerizations of alkenes and polyenes

Author:

Turque Oliver12345ORCID,Greer Alexander12345ORCID,Wauchope Orrette R.6735ORCID

Affiliation:

1. Department of Chemistry

2. Brooklyn College

3. City University of New York

4. Brooklyn

5. USA

6. Department of Natural Sciences

7. Baruch College

Abstract

Photogeneration of a peroxy intermediate leads to oxygen evolution along with regeneration of the compound as its isomer. The review is arranged to probe patterns of isomer arrangements (pun intended).

Funder

National Science Foundation

City University of New York

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference49 articles.

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2. Photochemical Reactions as Key Steps in Organic Synthesis

3. N. J. Turro , V.Ramamurthy and J. C.Scaiano , in Modern Molecular Photochemistry of Organic Molecules , University Science Books , Sausalito, CA , 2010 , pp. 705–746 and 1018–1031

4. Chemistry of singlet oxygen. XI. Cis-trans isomerization of carotenoids by single oxygen and a probable quenching mechanism

5. Type I and Type II Photosensitized Oxidation Reactions: Guidelines and Mechanistic Pathways

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