Studies on neptunium complexation with CMPO- and diglycolamide-functionalized ionic liquids: experimental and computational studies

Author:

Sengupta Arijit1234,Mohapatra Prasanta Kumar1234ORCID,Pathak Priyanath1234,Ghanty Tapan Kumar5264,Verboom Willem7891011

Affiliation:

1. Radiochemistry Division

2. Bhabha Atomic Research Centre

3. Mumbai-400 085

4. India

5. Theoretical Chemistry Section

6. Mumbai-400085

7. Laboratory of Molecular Nanofabrication

8. MESA+ Institute for Nanotechnology

9. University of Twente

10. 7500 AE Enschede

11. The Netherlands

Abstract

A CMPO-functionalized task-specific ionic liquid provided significantly greater extraction of Np4+ than of NpO22+, which is of interest for radioactive waste treatment.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference74 articles.

1. S. Ahrland , Solution Chemistry and Kinetics of Ionic Reactions, in The Chemistry of Actinide Elements, ed. J. J. Katz, G. T. Seaborg and L. R. Morss, Chapman and Hall, New York, 2nd edn, 1986, vol. 2, pp. 1480–1545

2. Recent advances on the chemistry of solvent extraction applied to the reprocessing of spent nuclear fuels and radioactive wastes

3. Aqueous Partitioning of Minor Actinides by Different Processes

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