Oxidized divinyl oligoacene-bridged diruthenium complexes: bridged localized radical characters and reduced aromaticity in bridge cores

Author:

Ou Ya-Ping12345,Zhang Jing678910,Hu Yuxuan678910,Yin Jun678910ORCID,Chi Chunyan111213ORCID,Liu Sheng Hua678910ORCID

Affiliation:

1. Key Laboratory of Functional Metal-Organic Compounds of Hunan Province

2. Key Laboratory of Functional Organometallic Materials of Hunan Province College

3. College of Chemistry and Material Science

4. Hengyang Normal University

5. Hengyang

6. Key Laboratory of Pesticide and Chemical Biology

7. Ministry of Education

8. College of Chemistry

9. Central China Normal University

10. Wuhan 430079

11. Department of Chemistry

12. National University of Singapore

13. Singapore

Abstract

A series of bimetallic ruthenium vinyl complexes 1–5 bridged by oligoacenes were synthesized and characterized in this study.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Hunan Province

China Scholarship Council

Education Department of Hunan Province

Hengyang Normal University

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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