Electronic engineering and oxygen vacancy modification of La0.6Sr0.4FeO3−δ perovskite oxide by low-electronegativity sodium substitution for efficient CO2/CO fueled reversible solid oxide cells-Reference-Cited by-同舟云学术

Electronic engineering and oxygen vacancy modification of La_0.6Sr_0.4FeO_3−δ perovskite oxide by low-electronegativity sodium substitution for efficient CO₂/CO fueled reversible solid oxide cells

Published:2024 Issue:6 Volume:26 Page:3202-3210
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Lin Wanbin¹,Li Yihang²^ORCID,Singh Manish³,Zhao Huibin¹,Yang Rui¹,Su Pei-Chen⁴^ORCID,Fan Liangdong¹^ORCID

Affiliation:

1. Department of New Energy Science & Technology, College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen 518060, Guangdong, China

2. Interdisciplinary Research Center of Smart Sensors, Academy of Advanced Interdisciplinary Research, Xidian University, Xi'an 710026, China

3. Department of Metallurgical and Materials Engineering, Indian Institute of Technology Patna, Bihta, Bihar 801106, India

4. School of Mechanical and Aerospace Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore

Abstract

Sodium doping increases oxygen vacancy concentration, modulates the electronic structure, and improves CO2 chemical adsorption, enabling superior CO2/CO reversible conversion.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/GC/D3GC04451C

Reference62 articles.

1. High‐Temperature CO 2 Electrolysis in Solid Oxide Electrolysis Cells: Developments, Challenges, and Prospects

2. Enhancing Electrochemical CO₂ Reduction on Perovskite Oxide for Solid Oxide Electrolysis Cells through In Situ A‐Site Deficiencies and Surface Carbonate Deposition Induced by Lithium Cation Doping and Exsolution

3. In situ passivation of Fe nanoparticles exsolved from perovskite cathodes through zinc doping for CO₂ electrolysis

4. Atomic‐Scale Insight into Exsolution of CoFe Alloy Nanoparticles in La 0.4 Sr 0.6 Co 0.2 Fe 0.7 Mo 0.1 O 3− δ with Efficient CO 2 Electrolysis

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