Nucleophilic addition and substitution at coordinatively saturated boron by facile 1,2-hydrogen shuttling onto a carbene donor-Reference-Cited by-同舟云学术

Nucleophilic addition and substitution at coordinatively saturated boron by facile 1,2-hydrogen shuttling onto a carbene donor

Published:2017 Issue:10 Volume:8 Page:7066-7071
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Auerhammer Dominic¹²³⁴⁵^ORCID,Arrowsmith Merle¹²³⁴⁵^ORCID,Braunschweig Holger¹²³⁴⁵^ORCID,Dewhurst Rian D.¹²³⁴⁵^ORCID,Jiménez-Halla J. Oscar C.¹²³⁴⁶^ORCID,Kupfer Thomas¹²³⁴⁵

Affiliation:

1. Institut für Anorganische Chemie

2. Julius-Maximilians-Universität Würzburg

3. 97074 Würzburg

4. Germany

5. Institute for Sustainable Chemistry & Catalysis with Boron

6. Departamento de Química

Abstract

Anionic organic sp³-, sp²- and sp-nucleophiles as well as neutral Lewis bases were shown to add to a coordinatively saturated cyclic (alkyl)(amino)carbene (cAAC) supported borane thanks to reversible transfer of a hydrogen atom from boron to the adjacent Lewis acidic cAAC carbene carbon atom.

Funder

Consejo Nacional de Ciencia y Tecnología

Alexander von Humboldt-Stiftung

Julius-Maximilians-Universität Würzburg

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/SC/C7SC03193A

Reference29 articles.

1. Borane Complexes of Trivalent Organophosphorus Compounds. Versatile Precursors for the Synthesis of Chiral Phosphine Ligands for Asymmetric Catalysis