A cobalt(ii) iminoiodane complex and its scandium adduct: mechanistic promiscuity in hydrogen atom abstraction reactions-Reference-Cited by-同舟云学术

A cobalt(ii) iminoiodane complex and its scandium adduct: mechanistic promiscuity in hydrogen atom abstraction reactions

Published:2016 Issue:37 Volume:45 Page:14538-14543
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kundu Subrata¹²³⁴,Chernev Petko⁵⁶⁷⁴,Engelmann Xenia¹²³⁴,Chung Chan Siu⁸⁹¹⁰¹¹,Dau Holger⁵⁶⁷⁴,Bill Eckhard¹²¹³⁴,England Jason⁸⁹¹⁰¹¹,Nam Wonwoo¹⁴¹⁵¹⁶¹⁷¹⁸,Ray Kallol¹²³⁴

Affiliation:

1. Humboldt-Universität zu Berlin

2. Institut für Chemie

3. D-12489 Berlin

4. Germany

5. Freie Universität Berlin

6. FB Physik

7. D-14195-Berlin

8. Division of Chemistry and Biological Chemistry

9. School of Physical and Mathematical Sciences

10. Nanyang Technological University

11. Singapore 637371

12. Max-Plank-Institut für Chemische Energiekonversion

13. D-45470 Mülheim an der Ruhr

14. Department of Chemistry and Nano Science

15. Center for Biomimetic System

16. Ewha Womans University

17. Seoul 120-750

18. Korea

Abstract

In addition to imidometal [Mⁿ⁺NR] units, transient metal–iminoiodane [M⁽ⁿ⁻²⁾⁺−N(R)IPh] adducts have been demonstrated as a possible “second oxidant” responsible for the imido group transfer reactivity.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT01815G

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