5-(2-Pyridil)-1H-tetrazole complexes with Mo(iv) and W(iv) cyanides
Author:
Affiliation:
1. Jagiellonian University in Kraków
2. Faculty of Chemistry
3. 30-060 Kraków, R. Ingardena 3
4. Poland
Abstract
The reactions of tetrazole ligand derived from 2-cyanopyridine with K3Na[Mo(CN)4O2]·6H2O and K3Na[W(CN)4O2]·6H2O in water–ethanol solution result in isolation of two new complexes with the following formulae: (PPh4)2[Mo(CN)3O(pdt)]·2H2O (1) (Hpdt = 5-(2-pyridil)-1H-tetrazole) and (PPh4)2[W(CN)3O(pdt)]·3H2O (2).
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/DT/C6DT04908G
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