Arene displacement, C–H activation and acetonitrile insertion reactions enabled by coordination of a functionalized iminophosphorane to a Ru<sup>II</sup>–<i>p</i>-cymene scaffold-Reference-Cited by-同舟云学术

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Arene displacement, C–H activation and acetonitrile insertion reactions enabled by coordination of a functionalized iminophosphorane to a Ru^II–p-cymene scaffold

Published:2024 Issue:25 Volume:53 Page:10693-10703
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Gourkhede Rani¹,Kaur Bhupinder¹,Kote Basvaraj S.¹,Balakrishna Maravanji S.¹^ORCID

Affiliation:

1. Phosphorus Laboratory, Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai 400076, India

Abstract

Reaction of iminophosphorano-phosphine with [Ru(η6-p-cymene)Cl2]2 yielded three different types of complex via CH activation, tethered η6-arene coordination, ortho-metallation or addition/insertion/cleavage/rearrangement reactions.

Funder

Indian Institute of Technology Bombay

CSIR – Indian Institute of Chemical Biology

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT00940A

Reference34 articles.

1. Late-stage ligand functionalization via the Staudinger reaction using phosphine-appended 2,2′-bipyridine

2. Facileo-quinodimethane formation from benzocyclobutenes triggered by the Staudinger reaction at ambient temperature

3. Sixty years of staudinger reaction

4. Über neue organische Phosphorverbindungen III. Phosphinmethylenderivate und Phosphinimine

5. Synthesis of new metallacycles of rhenium(VII) oxides: migration of trimethylsilyl group to form the cis-dioxo cyclometallaphosphoranimino phosphane NPPh2CH2PPh2Re(O)2(OSiMe3)2 and arsane NPPh2(CH2)2AsPh2Re(O)2(OSiMe3)2

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