Continuous addition kinetic elucidation: catalyst and reactant order, rate constant, and poisoning from a single experiment-Reference-Cited by-同舟云学术

Continuous addition kinetic elucidation: catalyst and reactant order, rate constant, and poisoning from a single experiment

Published:2023 Issue:36 Volume:14 Page:9970-9977
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Williams Peter J. H.¹,Killeen Charles¹,Chagunda Ian C.¹^ORCID,Henderson Brett¹,Donnecke Sofia¹,Munro Wil¹,Sidhu Jaspreet¹,Kraft Denaisha¹,Harrington David A.¹^ORCID,McIndoe J. Scott¹^ORCID

Affiliation:

1. Department of Chemistry, University of Victoria, PO Box 1700 STN CSC, Victoria, BC V8W 2Y2, Canada

Abstract

CAKE involves continuous injection of a catalyst to determine multiple kinetic parameters, including catalyst order, from one experiment, thus reducing the workload and avoiding the pot-to-pot reproducibility issues caused by catalyst poisoning.

Funder

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC02698A

Reference37 articles.

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4. M.Soustelle , An Introduction to Chemical Kinetics: Soustelle/An Introduction to Chemical Kinetics , John Wiley & Sons, Inc , Hoboken, NJ, USA , 2011

5. Mechanistic analysis by NMR spectroscopy: A users guide

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