Theoretical study of deuterium isotope effects on acid–base equilibria under ambient and hydrothermal conditions-Reference-Cited by-同舟云学术

Theoretical study of deuterium isotope effects on acid–base equilibria under ambient and hydrothermal conditions

Published:2015 Issue:12 Volume:5 Page:9097-9109
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Mora-Diez Nelaine¹²³⁴,Egorova Yulia¹²³⁴,Plommer Hart¹²³⁴,Tremaine Peter R.¹⁵⁶⁴

Affiliation:

1. Department of Chemistry

2. Thompson Rivers University

3. Kamloops

4. Canada

5. University of Guelph

6. Guelph

Abstract

The calculated difference between pK_a values in H₂O and D₂O is in excellent agreement with experiment.

Funder

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C4RA14087G

Reference61 articles.

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2. P. M. Laughton and R. E.Robertson, in Solute–Solvent Interactions, ed. J. F. Coetzee and C. D. Ritchie, Marcel Dekker, New York, 1969, ch. 7, and references there in

3. P. R. Tremaine , K.Zhang, P.Benezeth and C.Xiao, in Aqueous Systems at Elevated Temperatures and Pressures: Physical Chemistry in Water, Steam and Aqueous Solutions, ed. D. A. Palmer, R. Fernandez-Prini and A. H. Harvey, Elsevier Academic Press, Amsterdam, 2004, ch. 13

4. THE SECOND DISSOCIATION CONSTANT OF DEUTERIOSULFURIC ACID FROM 25 TO 225°

5. The ionization constant of heavy water (D2O) in the temperature range 298 to 523 K

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