Tandem catalytic allylic C–H amination and asymmetric [2,3]-rearrangement <i>via</i> bimetallic relay catalysis-Reference-Cited by-同舟云学术

Tandem catalytic allylic C–H amination and asymmetric [2,3]-rearrangement via bimetallic relay catalysis

Published:2024 Issue:33 Volume:15 Page:13299-13305
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Wu Zhenwei¹²,Yang Xi²,Zhang Fangqing¹,Liu Yangbin¹²,Feng Xiaoming²³^ORCID

Affiliation:

1. State Key Laboratory of Chemical Oncogenomics, Guangdong Provincial Key Laboratory of Chemical Genomics, Peking University Shenzhen Graduate School, Shenzhen, Guangdong, 518055, P. R. China

2. Institute of Chemical Biology, Shenzhen Bay Laboratory, Shenzhen, 518055, P. R. China

3. Key Laboratory of Green Chemistry & Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, P. R. China

Abstract

An asymmetric tandem allylic C–H amination and [2,3]-sigmatropic rearrangement has been developed by making use of bimetallic relay catalysis with an achiral Pd(0) catalyst and a chiral N,N′-dioxide-Mg(ii) complex.

Funder

National Natural Science Foundation of China

Shenzhen Bay Laboratory

Guangdong Provincial Pearl River Talents Program

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC03315A

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