ε-Caprolactone polymerization using titanium complexes immobilized onto silica based materials functionalized with ionic liquids: insights into steric, electronic and support effects

Author:

Cruz Paula12345,Pérez Yolanda12345,Hierro Isabel del12345,Fernández-Galán Rafael678910,Fajardo Mariano12345

Affiliation:

1. Departamento Biología y Geología

2. Física y Química Inorgánica (E.S.C.E.T.)

3. Universidad Rey Juan Carlos

4. Madrid

5. Spain

6. Departamento Química Inorgánica

7. Orgánica y Bioquímica

8. Facultad de Ciencias y Tecnologías Químicas

9. Universidad de Castilla-La Mancha

10. Campus Universitario de Ciudad Real

Abstract

Heterogeneous catalysts comprised of titanium immobilized on silica imidazolium-based systems have been synthesized for the ring opening polymerization of ε-caprolactone.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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