5-Fold symmetry in superatomic scandium clusters: exploiting favourable orbital overlap to sequester spin-Reference-Cited by-同舟云学术

5-Fold symmetry in superatomic scandium clusters: exploiting favourable orbital overlap to sequester spin

Published:2020 Issue:7 Volume:22 Page:4051-4058
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Gilmour J. T. A.¹²³⁴⁵^ORCID,Gaston N.¹²³⁴⁵^ORCID

Affiliation:

1. The MacDiarmid Institute for Advanced Materials and Nanotechnology

2. The Department of Physics

3. The University of Auckland

4. Private Bag 92019

5. Auckland 1142

Abstract

5-Fold symmetry axes in scandium clusters localise same spin electrons. This explains the anomalously high magnetic moment of scandium clusters with 5-membered rings and clarifies the role of d-electrons in the formation of superatomic states.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CP/C9CP05933D

Reference42 articles.

1. Electronic Shell Structure and Abundances of Sodium Clusters

2. Electronic Structure of the Superatom: A Quasiatomic System Based on a Semiconductor Heterostructure

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