Synthesis, crystal growth, physio-chemical characterization and quantum chemical calculations of NLO active metal–organic crystal: dibromo(4-hydroxy-l-proline)cadmium(ii) for non-linear optical applications

Author:

Boopathi K.1234ORCID,Babu S. Moorthy1234,Jagan R.5674,Athimoolam S.58294,Ramasamy P.1011124

Affiliation:

1. Crystal Growth Centre

2. Anna University

3. Chennai 600 025

4. India

5. Department of Physics

6. St. Joseph College of Engineering

7. Chennai 600119

8. University College of Engineering, Nagercoil

9. Nagercoil 629 004

10. SSN Research Centre

11. SSN College of Engineering

12. Kalavakkam 603110

Abstract

Single crystals of DB4HPC, a new metal–organic complex, have been grown from saturated solution for the first time. DB4HPC crystallizes in a monoclinic crystal system with noncentrosymmetric space group P21 and is thermally stable up to 240 °C.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference47 articles.

1. N. P. Prasad and D. J.Williams , Introduction to Nonlinear Optical Effects in Molecules and Polymers , Wiley , New York , 1991

2. Materials for Nonlinear Optics, Chemical Perspectives , ed. S. R. Marder , J. E. Sohn and G. D. Stucky , ACS Symposium Series 455, American Chemical Society , Washington DC , 1991

3. Nonlinear Optics of Organic Molecules and Polymers , ed. H. S. Nalwa and S. Miyata , CRC Press , Boca Raton, FL , 1997

4. Organometallic materials for nonlinear optics

5. S. R. Marder , in Inorganic Materials , ed. D. W. Bruce and D. O’Hare , Wiley , New York , 1992 , p. 116

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