Ultrafast dynamics and solvent-dependent deactivation kinetics of BODIPY molecular rotors-Reference-Cited by-同舟云学术

Ultrafast dynamics and solvent-dependent deactivation kinetics of BODIPY molecular rotors

Published:2017 Issue:30 Volume:19 Page:19998-20007
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Suhina Tomislav¹²¹³⁴,Amirjalayer Saeed⁵⁶⁷⁸⁹^ORCID,Woutersen Sander¹²¹³⁴,Bonn Daniel¹¹⁰¹¹¹¹²,Brouwer Albert M.¹²¹³⁴^ORCID

Affiliation:

1. University of Amsterdam

2. van 't Hoff Institute for Molecular Sciences

3. 1090 GD Amsterdam

4. The Netherlands

5. Center for Nanotechnology (CeNTech) and Physical Institute

6. University of Münster

7. Heisenbergstrasse 11

8. 48149 Münster

9. Germany

10. van der Waals-Zeeman Institute

11. Institute of Physics

12. 1090 GL Amsterdam

Abstract

The fluorescent excited state of a molecular rotor based on the meso-substituted boron-dipyrromethane (BODIPY) core decays rapidly to the ground state via a conical intersection. The fluorescence is strongly increased in viscous solvents, but solvent polarity has only a small effect.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CP/C7CP02037F

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