Hydroazidation of trifluoromethyl alkenes with trimethylsilyl azide enabled by organic photoredox catalysis

Author:

Shi Yutao1,Zhang Yuliang1,Ji Xiaochen12ORCID,Huang Huawen12ORCID

Affiliation:

1. Key Laboratory for Green Organic Synthesis and Application of Hunan Province, Key Laboratory of Environmentally Friendly Chemistry and Application of Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan 411105, China

2. School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, 453007, China

Abstract

A mild hydroazidation of trifluoromethyl alkenes with trimethylsilyl azide through organic photoredox catalysis was developed, delivering a series of valuable β-CF3-azides with exclusive selectivity.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Hunan Province

Scientific Research Foundation of Hunan Provincial Education Department

Henan Normal University

Publisher

Royal Society of Chemistry (RSC)

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