Coordination-induced reductive elimination from a titanium(<scp>iv</scp>) complex-Reference-Cited by-同舟云学术

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Coordination-induced reductive elimination from a titanium(iv) complex

Published:2024 Issue:68 Volume:60 Page:9030-9033
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Fritsche Paul¹,Geyer Lucia¹,Czernetzki Corinna¹^ORCID,Hierlmeier Gabriele¹^ORCID

Affiliation:

1. Julius-Maximilians-Universität Würzburg, Institut für Anorganische Chemie, Am Hubland, 97074 Würzburg, Germany

Abstract

Diamidopyridine-supported titanium dibenzyl complexes undergo coordination-induced C–C reductive elimination upon addition of alkynes and quantitative formation of titanacyclopentadienes.

Funder

Fonds der Chemischen Industrie

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC02500H

Reference34 articles.

1. J. F.Hartwig , Organotransition metal chemistry. From bonding to catalysis , University Science Books , Sausalito, Calif , 2010

2. Impact of Cross-Coupling Reactions in Drug Discovery and Development

3. Theoretical studies of oxidative addition and reductive elimination. 3. Carbon-hydrogen and carbon-carbon reductive coupling from palladium and platinum bis(phosphine) complexes

4. Mechanistic Investigation of Catalytic Carbon−Carbon Bond Activation and Formation by Platinum and Palladium Phosphine Complexes

5. Five-Coordinate Intermediates in Carbon−Carbon Reductive Elimination Reactions from Pt(IV)

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