Effects of functional groups in iron porphyrin on the mechanism and activity of oxygen reduction reaction

Author:

Dung Tran Phuong12,Chihaia Viorel3,Son Do Ngoc45ORCID

Affiliation:

1. Department of Chemistry, University of Science, Vietnam National University, Ho Chi Minh City, Vietnam

2. Department of Chemistry, Ho Chi Minh City University of Education, Ho Chi Minh City, Vietnam

3. Institute of Physical Chemistry “Ilie Murgulescu” of the Romanian Academy, Splaiul Independentei 202, Sector 6, 060021 Bucharest, Romania

4. Ho Chi Minh City University of Technology (HCMUT), 268 Ly Thuong Kiet Street, District 10, Ho Chi Minh City, Vietnam

5. Vietnam National University Ho Chi Minh City, Linh Trung Ward, Ho Chi Minh City, Vietnam

Abstract

–CH3 and –NH2 groups are the best substitutions for improving the activity of the oxygen reduction reaction. The nature of the interaction between the ORR intermediates and porphyrin substrates is charge exchange.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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