Transfer hydrogenation of nitroarenes with hydrazine at near-room temperature catalysed by a MoO2 catalyst-Reference-Cited by-同舟云学术

Transfer hydrogenation of nitroarenes with hydrazine at near-room temperature catalysed by a MoO2 catalyst

Published:2016 Issue:8 Volume:18 Page:2435-2442
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Zhang Chaofeng¹²³⁴⁵,Lu Jianmin¹²³⁴⁵,Li Mingrun¹²³⁴⁵,Wang Yehong¹²³⁴⁵,Zhang Zhe¹²³⁴⁵,Chen Haijun¹²³⁴⁵,Wang Feng¹²³⁴⁵

Affiliation:

1. State Key Laboratory of Catalysis

2. Dalian National Laboratory for Clean Energy

3. Dalian Institute of Chemical Physics

4. Chinese Academy of Sciences

5. Dalian 116023

Abstract

We present an experimental and computational study of the elementary steps of N₂H₄ hydrogen transfer on crystalline MoO₂, and demonstrate its unique bifunctional metallic-basic properties in a catalytic hydrogenation reaction.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/GC/C5GC02460A

Reference82 articles.

1. Selective Deoxygenation of Epoxides to Alkenes with Molecular Hydrogen Using a Hydrotalcite-Supported Gold Catalyst: A Concerted Effect between Gold Nanoparticles and Basic Sites on a Support

2. Efficient Subnanometric Gold-Catalyzed Hydrogen Generation via Formic Acid Decomposition under Ambient Conditions

3. Design of a Silver-Cerium Dioxide Core-Shell Nanocomposite Catalyst for Chemoselective Reduction Reactions

4. Highly Chemoselective Reduction of Nitroaromatic Compounds Using a Hydrotalcite-supported Silver-nanoparticle Catalyst under a CO Atmosphere

5. Size- and support-dependent silver cluster catalysis for chemoselective hydrogenation of nitroaromatics

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