Confined benzene within InOF-1: contrasting CO2 and SO2 capture behaviours

Author:

Barrios-Vargas Luz J.12345,Ruiz-Montoya José G.678910,Landeros-Rivera Bruno1112135,Álvarez J. Raziel12345ORCID,Alvarado-Alvarado Daniel12345,Vargas Rubicelia1112135ORCID,Martínez Ana23145ORCID,González-Zamora Eduardo1112135ORCID,Cáceres Ludy M.15161710,Morales Juan C.678910ORCID,Ibarra Ilich A.12345ORCID

Affiliation:

1. Laboratorio de Fisicoquímica y Reactividad de Superficies (LaFReS)

2. Instituto de Investigaciones en Materiales

3. Universidad Nacional Autónoma de México

4. 04510 Ciudad de México

5. Mexico

6. Laboratorio de Investigación de Electroquímica Aplicada

7. Facultad de Ciencias

8. Universidad Nacional de Ingeniería

9. Lima

10. Perú

11. Departamento de Química

12. Universidad Autónoma Metropolitana-Iztapalapa

13. C. P. 09340 Ciudad de México

14. Ciudad de México

15. Facultad de Ingeniería y Arquitectura

16. Universidad de Lima

17. Lima 1503

Abstract

Benzene confinement enhances the CO2 capture while decreases the SO2 capture within InOF-1 due to the competition among molecules for the preferential adsorption sites. Pore channel view of CO2Bz@InOF-1b (left) and SO2⋯Bz@InOF-1b (right) systems.

Funder

Universidad Nacional Autónoma de México

Consejo Nacional de Ciencia y Tecnología

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference44 articles.

1. National Oceanic and Atmospheric Administration (NOAA), Carbon dioxide levels hit record peak in May , https://research.noaa.gov/article/ArtMID/587/ArticleID/2461/Carbon-dioxide-levels-hit-record-peak-in-May

2. World Meteorological Organization (WMO), WMO Greenhouse Gas Bulletin (GHG Bulletin) No. 14, https://library.wmo.int/doc_num.php?explnum_id=5455

3. Metal–organic frameworks for the control and management of air quality: advances and future direction

4. S. Kaskel , The Chemistry of Metal-Organic Frameworks: Synthesis, Characterization, and Applications , Wiley-VCH , Weinheim , 2016

5. D. Farrusseng , Metal-Organic Frameworks: Applications from Catalysis to Gas Storage , Wiley-VCH , Weinheim , 2011

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