FLP behaviour of cationic titanium complexes with tridentate Cp,O,N-ligands: highly efficient syntheses and activation reactions of C–X bonds (X = Cl, F)-Reference-Cited by-同舟云学术

FLP behaviour of cationic titanium complexes with tridentate Cp,O,N-ligands: highly efficient syntheses and activation reactions of C–X bonds (X = Cl, F)

Published:2019 Issue:4 Volume:48 Page:1516-1523
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Fischer Malte¹²³⁴⁵^ORCID,Schwitalla Kevin¹²³⁴⁵,Baues Svenja¹²³⁴⁵,Schmidtmann Marc¹²³⁴⁵^ORCID,Beckhaus Ruediger¹²³⁴⁵^ORCID

Affiliation:

1. Institut fuer Chemie

2. Fakultaet für Mathematik und Naturwissenschaften

3. Carl von Ossietzky Universitaet Oldenburg

4. 26111 Oldenburg

5. Germany

Abstract

Titanium FLPs! Solvent- and catalyst-free Aza-Michael reaction provides β-amino ketones which were employed as ligand precursors for the convenient synthesis of novel cationic titanium complexes with tridentate Cp,O,N-ligand frameworks, which activate C–X bonds in a FLP-like manner.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C8DT04707C

Reference66 articles.

1. Reversible, Metal-Free Hydrogen Activation

2. Frustrated Lewis Pairs I and II, Uncovering and Understanding/Expanding the Scope , in Topics in Current Chemistry , ed. G. Erker and D. W. Stephan , Springer , Heidelberg, New York, Dordrecht, London , 2013 , vol. 332/334

3. The broadening reach of frustrated Lewis pair chemistry

4. Frustrated Lewis Pair Chemistry: Development and Perspectives

5. Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

Cited by 13 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. From Coordination to Noncoordination: Syntheses and Substitution Lability Studies of Titanium Triflato Complexes;Inorganic Chemistry;2024-07-26

2. Pendulum-like hemilability in a Ti-based frustrated Lewis Trio;Chemical Science;2024

3. Synthesis and Characterization of Zr and Hf Triazenido Complexes with Rare κ¹N-Coordination Built Directly in the Coordination Sphere of the Metal;Organometallics;2023-01-10

4. Recent progress in the chemistry of β-aminoketones;RSC Advances;2022

5. A niobium pentafulvene ethylene complex: synthesis, properties and reaction pathways;Dalton Transactions;2022