FLP behaviour of cationic titanium complexes with tridentate Cp,O,N-ligands: highly efficient syntheses and activation reactions of C–X bonds (X = Cl, F)
Author:
Affiliation:
1. Institut fuer Chemie
2. Fakultaet für Mathematik und Naturwissenschaften
3. Carl von Ossietzky Universitaet Oldenburg
4. 26111 Oldenburg
5. Germany
Abstract
Titanium FLPs! Solvent- and catalyst-free Aza-Michael reaction provides β-amino ketones which were employed as ligand precursors for the convenient synthesis of novel cationic titanium complexes with tridentate Cp,O,N-ligand frameworks, which activate C–X bonds in a FLP-like manner.
Funder
Deutsche Forschungsgemeinschaft
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C8DT04707C
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